Interactions des alcynes avec les complexes carbéniques du tungstène portant une double liaison carbone— carbone: Accès aux dérivés bicyclo[4,1,0]. Download Citation on ResearchGate | Réaction des halogenures de titane(IV) avec les alcynes: Formation d’halogénoalcènes | The behaviour of some mono-. Download Citation on ResearchGate | Action du chlorure de fer(III) sur les alcynes: Reduction du fer(III) en fer(II) et formation d’un chloro-alcene | The behaviour.
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Comparison of three enoate reductases and their potential use for biotransformations. Access to the PDF text. Substrate zlcynes and enantioselectivity of 4-hydroxyacetophenone monooxygenase. If you want to subscribe to this journal, see our rates You can purchase this item in Lds Per View: Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis.
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Catalytic addition of diazoalkane carbene to propargylic compounds: Top of the page – Article Outline. In addition, the results of the theoretical investigation of Chapter 2 are exploited to show how changes in the phosphorus substituents can be used to fine tune regioselectivity of alkyne cycloadditions without modifying the substituents on the final product. These 1,3-dipoles have been previously demonstrated to be accessible in a one-pot reaction of imines, acid chlorides and organophosphorus reagents, and participate in 1,3-dipolar cycloaddition reactions.
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CHIM – Chimie organique II – Acalog ACMS™
Short chain volatile isoprene hydrocarbon production using the mevalonic acid pathway in genetically engineered yeast and fungi. EP Kind code of ref document: Catalytic addition of diazoalkane carbene to enynes: All items in eScholarship McGill are protected by copyright with all rights reserved unless otherwise indicated. Importantly, these 1,3-dipoles display divergent regioselectivity, which can be exploited to synthesize a variety of pyrroles with high selectivity through the use of the appropriate reactant.
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US USA1 en Enantioselective reduction of carbonyl compounds by whole-cell biotransformation, combining a formate dehydrogenase and a R -specific alcohol dehydrogenase. In addition, the reaction proceeds with high diastereo- and regioselectivity. Direct route to alkenyl alkylidene bicyclohexane derivatives.
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If you are a subscriber, please sign in ‘My Account’ at the top right aocynes the screen. As per the Law relating to information akcynes and personal integrity, you have the right to oppose art 26 of that lawaccess art 34 of that law and rectify art 36 of that law your personal data.
Personal information regarding our website’s visitors, including their identity, is confidential. Access to the full text of this article requires a subscription. Enynes with terminal triple bond lead to alkenyl bicyclo[x.
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CHIM 263 – Chimie organique II
While each of the dipoles are established to participate in 1,3-dipolar cycloaddition reactions, until now, no general rules regarding the factors that control regioselectivity have been described.
Contact Help Who are we? Cycloaddition reactions of the above mentioned dipoles are examined with a range of unsymmetrical electron poor and electron rich alkynes, and by comparing the behavior of these related dipoles, trends are observed in regioselectivity that relates to the alkyne ionization potential. Deposit your publication Prepare your thesis Ask a librarian Feedback. The utility of this reaction has been extended to other products, including in situ reduction of the 2-pyrroline to pyrolidines, or oxidation to form pyrroles.
Malonyl-coenzyme A reductase in the modified 3-hydroxypropionate cycle for autotrophic carbon fixation in archaeal Metallosphaera and Sulfolobus spp. Catalysis, Ruthenium, Diazo compounds, Carbene, Alkynes.
Simple alkynes generate dienes via double diazoalkane carbene addition to the triple bond. Conjointement avec le Pr. Polycyclic 2-pyrrolines are generated in rapid cycloaddition reactions, in a modular fashion from easily accessible starting materials: X-ray crystallographic studies demonstrate the significant role of the PR3 unit on the ground state structure of these dipoles and their reactivity.
Title Creator Subject Faculty Date. Country alcybes ref document: The objective of the research described in this thesis is to both understand the reactivity of these dipoles, and exploit their cycloaddition with alkynes and alkenes to synthesize pyrroles and 2-pyrrolines with high regio- diastereo- and enantioselectivity.
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Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons. Propargylic carboxylates lead to conjugated dienes by coupling of the diazoalkane carbene with the alkyne terminal carbon and 1,2-shift of the carboxylate.
As such, this provides a straightforward approach to control chirality in 1,3-dipolar cycloaddition reactions.